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开放的复杂巨系统 4

合成 2

思维科学 2

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9 + 2结构 1

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One-pot three-component Mannich reaction catalyzed by sucrose char sulfonic acid

Qiong XU, Zhigao YANG, Dulin YIN, Jihui WANG

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 201-205 doi: 10.1007/s11705-009-0052-5

摘要： Sucrose char sulfonic acid efficiently catalyzed the one-pot three-component Mannich reaction of ketones, aromatic aldehydes and amines in ethanol to afford the corresponding -amino carbonyl compounds in good to excellent yields. A series of heteroaromatic -amino carbonyl compounds can be obtained when using 2-acetylpyrazine as substrate. This reaction can be performed under mild reaction conditions with clean reaction profiles and a simple workup procedure.

关键词： One–pot synthesis b-amino ketone char sulfonic acid 2-acetylpyrazine catalysis

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One-step synthesis of

Kuiyi YOU, Fangfang ZHAO, Xueyan LONG, Pingle LIU, Qiuhong AI, Hean LUO

《化学科学与工程前沿（英文）》 2012年第6卷第4期页码 389-394 doi: 10.1007/s11705-012-1218-0

摘要： A simple and efficient approach for the synthesis of -caprolactam via the liquid phase nitrosation of cyclohexane and nitrosyl sulfuric acid in the presence of concentrated sulfuric acid has been developed. A series of novel AlVPO composites were prepared by an impregnation method and the composites were then employed to catalyze the nitrosation reaction of cyclohexane and nitrosyl sulfuric acid. Compared to the reaction using fuming sulfuric acid, the selectivity for the desired product was significantly improved using this one-step catalytic process. This method affords a shortcut to prepare -caprolactam and its analogs from cyclohexane.

关键词： cyclohexane ?-caprolactam AlVPO composite catalysts one-step synthesis concentrated sulfuric acid

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One-pot hydrothermal fabrication of BiVO/FeO/rGO composite photocatalyst for the simulated solar light-driven

《环境科学与工程前沿（英文）》 2022年第16卷第3期 doi: 10.1007/s11783-021-1470-y

摘要：

• BiVO₄/Fe₃O₄/rGO has excellent photocatalytic activity under solar light radiation.

关键词： Photocatalysis Ternary magnetic photocatalyst Visible-light-driven Free radicals trapping Reusability Recycling

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One-pot preparation of graphene oxide magnetic nanocomposites for the removal of tetrabromobisphenol

Liqin JI, Xue BAI, Lincheng ZHOU, Hanchang SHI, Wei CHEN, Zulin HUA

《环境科学与工程前沿（英文）》 2013年第7卷第3期页码 442-450 doi: 10.1007/s11783-013-0515-2

摘要： A simple solvothermal method was used to prepare monodisperse magnetite (Fe O ) nanoparticles attached onto graphene oxide (GO) sheets as adsorbents to remove tetrabromobisphenol A (TBBPA) from an aqueous solution. These Fe O /GO (MGO) nanocomposites were characterized by transmission electron microscopy. The adsorption capacity at different initial pH, contact duration, and temperature were evaluated. The kinetics of adsorption was found to fit the pseudo-second-order model perfectly. The adsorption isotherm well fitted the Langmuir model, and the theoretical maximum of adsorption capacity calculated by the Langmuir model was 27.26 mg?g . The adsorption thermodynamics of TBBPA on the MGO nanocomposites was determined at 303 K, 313 K, and 323 K, respectively. The results indicated that the adsorption was spontaneous and endothermic. The MGO nanocomposites were conveniently separated from the media by an external magnetic field within several seconds, and then regenerated in 0.2 M NaOH solution. Thus, the MGO nanocomposites are a promising candidate for TBBPA removal from wastewater.

关键词： Magnetic graphene oxide (GO) adsorption tetrabromobisphenol A (TBBPA)

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One-step synthesis of recoverable CuCo

Tongzhou Lu, Yongzheng Zhang, Chun Cheng, Yanbin Wang, Yongming Zhu

《化学科学与工程前沿（英文）》 2020年第14卷第4期页码 595-604 doi: 10.1007/s11705-019-1818-z

摘要： A facile one-step hydrothermal method has been adopted to directly synthesize the CuCo S material on the surface of Ni foam. Due to the relatively large specific surface area and wide pore size distribution, the CuCo S material not only effectively increases the reactive area, but also accommodates more side reaction products to avoid the difficulty of mass transfer. When evaluated as anode for Li-ion batteries, the CuCo S material exhibits excellent electrochemical performance including high discharge capacity, outstanding cyclic stability and good rate performance. At the current density of 200 mA·g , the CuCo S material shows an extremely high initial discharge capacity of 2510 mAh·g , and the cycle numbers of the material even reach 83 times when the discharge capacity is reduced to 500 mAh·g . Furthermore, the discharge capacity can reach 269 mAh·g at a current of 2000 mA·g . More importantly, when the current density comes back to 200 mA·g , the discharge capacity could be recovered to 1436 mAh·g , suggesting an excellent capacity recovery characteristics.

关键词： copper cobalt sulfide recoverability one-step hydrothermal method anode material Li-ion battery

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Design, synthesis and HIV-RT inhibitory activity of novel thiazolidin-4-one derivatives

Hua CHEN, Zaihong GUO, Qingmei YIN, Xiaoxu DUAN, Yunjing GU, Xiaoliu LI

《化学科学与工程前沿（英文）》 2011年第5卷第2期页码 231-237 doi: 10.1007/s11705-010-1022-7

摘要： A series of 2-aryl-3-(4,5,6-trimethylpyrimidin-2-yl) thiazolidin-4-ones ( – ) and their derivatives bearing a lipophilic substituent, like acetoxy group ( – ), propionyloxy group ( – ), methyl ( and ) at C-5 on thiazolidin-4-one ring were designed, synthesized and evaluated for their HIV-RT inhibitory activity. Using self-catalyzed Pummerer reaction, compounds – and – were obtained in good yield (63.1% 75.2%). Preliminary anti-HIV-RT test of these derivatives indicated that compounds – , (propionyloxy group at C-5) showed moderate HIV-RT inhibitory activity and compounds and with methyl at C-5 showed a weak HIV-RT inhibitory activity. Structure activity relationship analysis suggested that the substituted groups on C-5 would be unfavorable to anti-HIV-RT activity and that the steric effect might play a critical role in the anti-HIV RT activity.

关键词： 5-subsituted thiazolidin-4-ones Pummerer reaction anti-HIV-RT activity SARs

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Microwave-assisted synthesis and antimicrobial activities of 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin

Hua CHEN, Yanan LI, Jie BAI, Lian ZHAO, Xiangguo YUAN, Xiaoliu LI, Keqiang CAO

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 186-191 doi: 10.1007/s11705-009-0004-0

摘要： 2-aryl-3-(naphthalene-1 or 2-yl)-1,3-thiazolidin-4-ones and were synthesized in 41%-67% yield by using microwave-assisted one-pot protocol. The structures of the new compounds , , , , , , and - were confirmed by IR, NMR, MS, and elemental analysis. The antimicrobial activities of the compounds against pv. lachrymans (Smith et Bryan) Young, Dye & Wilkie, Pers., and Blum. were examined. Some of the compounds showed good antifungical activity against Blum.

关键词： microwave-assisted synthesis naphthyl thiazolidin-4-one antimicrobial

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An Internet-of-Things Initiative for One Belt One Road (OBOR)

Li Da Xu

《工程管理前沿（英文）》 2016年第3卷第3期页码 206-223 doi: 10.15302/J-FEM-2016039

摘要： A wide range of industrial Internet of Things (IoT) applications have been developed and deployed in recent years. IoT has provided a promising opportunity to build powerful industrial systems and applications by leveraging the growing ubiquity of RFID, wireless, mobile and sensor devices. In an effort to understand the development of IoT in industries, this paper reviews the current research of IoT, key enabling technologies, major IoT applications in industries, and identifies research trends and challenges. As IoT has received support from governments and businesses across the globe, IoT will also greatly impact One Belt One Road (OBOR) in foreseeable future.

关键词： Internet of Things (IoT) RFID Wireless Sensor Networks Near Field Communications ICT

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单自由度平面闭链机构构型方法的研究

张美麟,张晔,杨治义

《中国工程科学》 2002年第4卷第6期页码 5-8

摘要：

提出了一种关于自由度平面闭链机构的构型方法，即“平面图形构造方法”。利用这种方法进行机构结构综合的主要过程是：先根据机械功能确定运动链的组成成分；再按这些成分构造平面图；最后在平面图上进行机构的构型和变异，并将其中结构最优者转换为机构简图。

关键词：机构运动链平面图

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Responses to emerging and re-emerging infectious diseases: One world, One health

null

《医学前沿（英文）》 2018年第12卷第1期页码 1-2 doi: 10.1007/s11684-018-0619-y

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“一带一路”战略背景下的北极航线开发利用

刘惠荣

《中国工程科学》 2016年第18卷第2期页码 111-118 doi: 10.15302/J-SSCAE-2016.02.014

摘要：

为了研究北极冰融加速环境下我国开展北极航线商业通航的价值意义，本文通过对传统航线与北极航线的成本效益比较分析，运用制度分析法考察了北极航线利用所面临的严峻挑战。提出北极航线开发利用应当纳入“一带一路”战略规划之中，北极航线可以成为延伸丝绸之路经济带的海上通道、21世纪海上丝绸之路的拓展航线、对外经贸网络不可或缺的组成部分，“一带一路”战略不应忽视开发利用北极航线的战略价值。

关键词：一带一路北极航线成本优势战略价值

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Validation of a steel dual-core self-centering brace (DC-SCB) for seismic resistance: from brace member to one-storyone-bay braced frame tests

Chung-Che CHOU,Ping-Ting CHUNG,Tsung-Han WU,Alexis Rafael Ovalle BEATO

《结构与土木工程前沿（英文）》 2016年第10卷第3期页码 303-311 doi: 10.1007/s11709-016-0347-9

摘要： A steel dual-core self-centering brace (DC-SCB) is an innovative structural member that provides both energy dissipation and self-centering properties to structures, reducing maximum and residual drifts of structures in earthquakes. The axial deformation capacity of the DC-SCB is doubled by a parallel arrangement of two inner cores, one outer box and two sets of tensioning elements. This paper presents cyclic test results of a DC-SCB component and a full-scale one-story, one-bay steel frame with a DC-SCB. The DC-SCB that was near 8 m-long was tested to evaluate its cyclic behavior and durability. The DC-SCB performed well under a total of three increasing cyclic loading tests and 60 low-cycle fatigue loading tests without failure. The maximum axial load of the DC-SCB was near 1700 kN at an interstory drift of 2.5%. Moreover, a three-story dual-core self-centering braced frame (DC-SCBF) with a single-diagonal DC-SCB was designed and its first-story, one-bay DC-SCBF subassembly specimen was tested in multiple earthquake-type loadings. The one-story, one-bay subassembly frame specimen performed well up to an interstory drift of 2% with yielding at the column base and local buckling in the steel beam; no damage of the DC-SCB was found after all tests. The maximum residual drift of the DC-SCBF caused by beam local buckling was 0.5% in 2.0% drift cycles.

关键词： dual-core self-centering brace (DC-SCB) braced frame tests residual deformation

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Talin and kindlin: the one-two punch in integrin activation

null

《医学前沿（英文）》 2014年第8卷第1期页码 6-16 doi: 10.1007/s11684-014-0317-3

摘要：

Proper cell-cell and cell-matrix contacts mediated by integrin adhesion receptors are important for development, immune response, hemostasis and wound healing. Integrins pass trans-membrane signals bidirectionally through their regulated affinities for extracellular ligands and intracellular signaling molecules. Such bidirectional signaling by integrins is enabled by the conformational changes that are often linked among extracellular, transmembrane and cytoplasmic domains. Here, we review how talin-integrin and kindlin-integrin interactions, in cooperation with talin-lipid and kindlin-lipid interactions, regulate integrin affinities and how the progress in these areas helps us understand integrin-related diseases.

关键词： signal transduction transmembrane domain nanodisc integrin talin kindling cell adhesion

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All-in-one functional supramolecular nanoparticles based on pillar[5]arene for controlled generation,

《化学科学与工程前沿（英文）》 2023年第17卷第3期页码 307-313 doi: 10.1007/s11705-022-2216-5

摘要： The storage and controlled release of singlet oxygen (¹O₂) have attracted increasing attention due to the wide application and microsecond lifetime of ¹O₂ in water. Herein we provide an integrated nanoplatform consisting of a diphenylanthracene derivative, a water-soluble pillar[5]arene and a photosensitizer tetrakis(4-hydroxyphenyl)porphyrin (TPP), that may provide the controlled generation, storage and release of singlet oxygen. We design a new diphenylanthracene derivative with two trimethylammonium bromide groups on both ends that can be well recognized by the pillar[5]arene. The formed nanocarriers can be used to load TPP through their supramolecular self-assembly. The resulting nanoparticles show good water-solubility and uniform spherical morphology. After laser irradiation (660 nm), the nanoparticles exhibit excellent ability for the generation and storage of ¹O₂. When the irradiated nanoparticles are heated above 80 °C, ¹O₂ can be released from the system. Therefore, in this paper we pioneer the use of noncovalent interaction to integrate the diphenylanthracene derivatives and photosensitizers into one functional system, which provides a new strategy for the controlled generation, storage and release of singlet oxygen. We believe this groundbreaking strategy will have a great potential in providing necessary amounts of ¹O₂ for the photodynamic therapy of tumors in dark.

关键词： storage and controlled release of singlet oxygen supramolecular nanoparticles noncovalent interactions pillararenes diphenylanthracene photosensitizers

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concentration of carboxymethyl cellulose on morphology of hydroxyapatite nanoparticles as prepared with one-step

Ruiqiang LIU,Rattan LAL

《环境科学与工程前沿（英文）》 2015年第9卷第5期页码 804-812 doi: 10.1007/s11783-015-0785-y

摘要： Nano-sized apatite particles (nAP) synthesized with carboxymethyl cellulose (CMC) have shown great application potentials in in situ heavy metal remediation. However, differences in CMC’s properties effects on the size of nAP produced are not well understood. In this paper, two types of CMC, with respective molecular weights (MW) of ~120000 and ~240000 Dalton or respective polymerization degrees of 500 (CMC-500) and 1050 (CMC-1050), were studied in a concentration range of 0.05%–0.5% (w/w) for nAP synthesis. Morphology of the particles was characterized with transmission electron microscopy (TEM). Results showed that 0.05% CMC-500 solution gave an average particle size of 148.7±134.9 nm, 0.25% CMC-500 solution produced particles of 21.8±20.4 nm, and, 0.5% CMC-500 solution contained particles of 15.8±7.7 nm. In comparison, 0.05% CMC-1050 solution produced nanoparticles of 6.8±3.2 nm, 0.25% CMC-1050 produced smaller nAP of 4.3±3.2 nm, and 0.5% CMC-1050 synthesized the smallest nanoparticles in this study, with an average diameter of 3.0±2.1 nm. Chemical composition of the products was identified with X-ray diffraction (XRD) as pure hydroxyapatite. Interactions between nAP and CMC were discussed with help of attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopic data. This study showed that CMC at higher concentration as well as higher MW facilitated to produce finer nanoparticles, showing that nAP size could be manipulated by selecting appropriate CMC MW and/or applying appropriate CMC concentration.

关键词： nanotechnology nanoparticles apatite carboxymethyl cellulose (CMC) particle size